Optimal experiment design: Link between the concentration and the accuracy of estimation of aggregation parameters
2016
Abstract The principal condition for optimal experiment design, required for getting reasonable error for equilibrium aggregation constant, K , determination is obtained. This condition states that the selected concentration range for performing titration experiment should be inversely proportional to the expected value of K . As a consequence, the choice of physico-chemical methods for determination of aggregation parameters must obey this condition.
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