Solid-solid phase-change materials with excellent mechanical property and solid state plasticity based on dynamic urethane bonds for Thermal Energy Storage

Abstract Solid-solid phase change materials (SSPCMs) with small volume change and leak-proof characteristic during the whole process of phase change play a vital role in development of PCM for thermal energy storage (TES). However, the non-recyclability of the materials due to their permanent cross-linking networks limited their practical application. Herein, a dynamic urethane bond cross linked SSPCM with PEG as phase change functional segments was successfully fabricated which was in solid state even at 130°C.Meantime, it exhibited excellent solid-state plasticity, resulting from dynamic urethane bond exchange. Moreover, the dynamic behavior of urethane bond in SSPCMs was firstly investigated. The topology freezing transition temperature (Tv) is about 113°C and the relaxation activation energy of SSPCM is calculated to be about 90 kJ/mol. The crystalline PEG endows SSPCM with high enthalpy value (reached up to 85 J/g), meantime, the cross-linked structure endows SSPCMs with remarkable mechanical flexibility (possess ultra-stretchability of 600%), thermal reliability and chemical stability. The combined thermal storage ability, appealing recyclability and flexibility endow the SSPCM promising application in the field of TES.