Tetraphenylphosphonium (Hydrogensulfido-S)trisulfidotungstate(VI)

The cations and anions of the title compound, [(C6H5)4P][W(HS)S3], are separated by normal van der Waals distances. The ions each lie on \overline{4} sites, such that the H atom of the anion is disordered over four sites with 0.25 occupancies. The W—S distances in the anion are 2.171 (2) A, with S—W—S angles of 108.1 (1) and 112.4 (2)°. In the cation, identical P—C distances of 1.793 (6) A are observed, with C—P—C angles of 106.3 (4) and 111.1 (2)°.