Interparticle Interactions in Colloidal Systems: Toward a Comprehensive Mesoscale Model

Intermolecular interactions control the collective behavior of colloidal clusters. The overwhelming majority of literature focuses on cohesive attributes of intermolecular forces as they govern the jamming process. However, the overlooked sliding component plays a critical role in the slow relaxation dynamics of colloidal aggregates and the emergence of discontinuous shear thickening in dense suspensions. Here, we use crystalline calcium–silicate–hydrate (C–S–H) as a model system to explore synergistic cohesive and sliding interactions. We use the free energy perturbation approach to reconstruct potential of mean force profile between two finite-sized nanolayers in an aqueous environment. We show that sliding free energy barriers decay exponentially as the separation distance increases. The characteristic length scale of the decay is related to the interface corrugation. We introduce a simple yet effective mechanism to capture the sliding behavior of colloids with surface roughness. Moreover, we develop a...