Crystal Structures of 1-Benzoyl-2-hydroxy-7-methoxynaphthalene Analogues: Dimeric Features of the Molecular Packing
2014
Molecular alignments of 1-aroyl-2-hydroxy-7-methoxynaphthalene analogues are classified into two groups, i.e., molecular stacking standing one behind another and dimeric aggregates. In single molecular structures, the 1-aroyl-2-hydroxy-7-methoxynaphthalene analogues show apparently same spatial organizations. The carbonyl groups in these molecules form intramolecular O–H…O=C hydrogen bonds with the adjacent hydroxy groups, affording six-membered cyclic structures. The aroyl groups constrained by the intramolecular hydrogen bonds essentially induce dimeric aggregates via formation of a pair of inter molecular O–H…O=C hydrogen bonds. When interactions led by the substituents of the benzene rings reduce the stability by the inter molecular O–H…O=C hydrogen bonds, the molecular packing should turn one-behind-one type piling.
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