Reducing Set Retardation in High-Volume Fly Ash Mixtures with the Use of Limestone

2012 
High-volume fly ash (HVFA) concretes are attractive not only because they reduce cement content and the associated greenhouse gases, but also because they avoid landfilling excessive quantities of fly ash. These sustainability benefits are often tempered by practical constructability limitations that may exist for HVFA concretes: retardation and diminution of the early-age reaction, delay in setting (and finishing operations), and lower early-age strength. This paper explores the alleviation of these deficiencies in HVFA mixtures by the incorporation of fine limestone powders into ternary blends. Isothermal calorimetry and Vicat needle penetration measurements are employed to assess reaction rates and setting times, respectively. A systematic variation of the content and fineness of the limestone powder in mixtures containing either a Class C or a Class F fly ash indicates that setting times are linearly correlated with the surface area supplied by the limestone. Comparison of a limestone system to a syst...
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