Sulfide glass fibers for infrared transmission

1981 
Abstract Germanium sulfide glasses were drawn into fibers with optical losses lower than 1 dB/m. The glass fibers were coated with Teflon FEP or silicone resin according to their thermal properties. Loss increase caused by coating was not observed. The main problems in obtaining low-loss fibers were investigated. Sulphur evolution in fiber drawing was avoided by choosing the appropriate glass compositions and drawing conditions, OH and SH impurities were reduced to 1 4 of initial values using the S 2 Cl 2 chemical reaction with water at 400–600°C. The possibility of ultra-low loss fibers using sulfide glasses is discussed in terms of intrinsic losses and impurity-related absorption losses.
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