Reaction of achiral titanium Z-enolates with chiral α-silyloxy aldehydes
1999
Abstract Aldol reactions between the putative Z -enolate derived from 2-methyl-3-pentanone and several chiral α- tert -butyldiphenylsilyloxy aldehydes have been studied. The stereochemical outcome suggests that stereoelectronic effects play a dominant role in these reactions and the results can be accommodated by the Felkin model, with gauche pentane interactions being less important.
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