Eco‐Friendly Solvents for Palladium‐Catalyzed Desulfitative C—H Bond Arylation of Heteroarenes.

Anoir Hfaiedh,Kedong Yuan,Hamed Ben Ammar,Béchir Ben Hassine,Jean-François Soulé,Henri Doucet

Eco‐Friendly Solvents for Palladium‐Catalyzed Desulfitative C—H Bond Arylation of Heteroarenes.

2015

Anoir Hfaiedh
Kedong Yuan
Hamed Ben Ammar
Béchir Ben Hassine
Jean-François Soulé
Henri Doucet

Using arylsulfonyl chlorides, arylation proceeds with remarkable regioselectivity: furans, benzofurans and N-alkyl/phenyl-pyrrols give C2-arylated products while thiophenes and benzothiophenes give the C3-arylated products.

Keywords:

Environmentally friendly
Hydrogen bond
Regioselectivity
Palladium
Catalysis
Organic chemistry
Chemistry
thiophene derivatives
pyrrole derivatives
c h bond

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