Janus bis(NHCs) tuned by heteroatom-bridge oxidation states
2020
Synthesis of the first tricyclic bis(carbenes) with facially opposed imidazole-2-ylidenes and two linking phosphorus centres in different oxidation states is presented using a modular, high-yield synthetic route. The formation of homo bimetallic coinage metal complexes provides a glimpse on their potential use.
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