Highly Efficient Photocatalytic and Antimicrobial AgGaCl Tri-Doped ZnO Nanorods for Water Treatment under Visible Light Irradiation

The aim of the present study is to analyze the synergy of antimicrobial elements, such as Ga, Ag and Cl by incorporating them in ZnO nanorods and measuring their antimicrobial and photocatalytic activity under visible light irradiation for water treatment. AgGa-doped ZnO nanorods and AgGaCl-doped ZnO nanorods on polyethylene substrate were prepared by a simple and fast microwave assisted synthesis. HCl was used in order to lower the pH of the precursor solution and favor Ga and Cl incorporation in the ZnO nanorods. The synthesized undoped and doped ZnO nanorods were analyzed with SEM, EDX, XRD and CL. The photocatalytic properties of the nanorods were evaluated via methylene blue degradation under visible light irradiation. Antimicrobial activity of the nanorods was measured via growth kinetics of Vibrio parahaemolyticus. It was found that AgGaCl-doped ZnO nanorods improve the methylene blue photo-degradation and above all, the antimicrobial activity of the AgGaCl tri-doped ZnO nanorods showed a lethal effect on the bacteria’s growth. This work shows that AgGaCl NRs are an excellent alternative for the development of sustainable water treatment devices and antimicrobial applications.