Recovery of aconitic and lactic acids from simulated aqueous effluents of the sugar-cane industry through liquid-liquid extraction

The recovery of aconitic and lactic acids from dilute aqueous effluents of the sugar-cane industry by a solvent extraction technique has been investigated in order to reduce environmental pollution and in view of the possible uses of pure solutes in the field of foods and pharmaceuticals. Reactive extraction of carboxylic acids with tributylphosphate dissolved in dodecane was examined. Experiments were performed at 25 °C for three extractant concentrations of 50%, 60% and 70% (mass %) in dodecane. The decrease of specific gravity and viscosity of solvent resulting from the presence of an inert diluent was favourable to the phase settling and the mass transfer. The percentage of acids recovered in the organic phase for a volumetric solvent ratio varying from 0.5 to 5.0 was determined. Taking into account the difference between the partition coefficients for the carboxylic acids under consideration, the selectivity of solvent with regard to aconitic acid also was quantified. Moreover, owing to its water-insolubility, its availability and its low cost, tributylphosphate can be considered as a promising extractant for large-scale applications. © 2000 Society of Chemical Industry