The total synthesis of rifamycin W
1990
Abstract The first total synthesis of rifamycin W ( 1 ) has been accomplished by coupling two segments of the aliphatic ansa-chain 40 and the aromatic chromophore 12 . The totally enantiospecific sequence elucidates the configurations of the C28 position and the C12 - C29 double bond to be R and E , respectively.
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