Effect of Mg Addition on Nucleation of Intra-granular Acicular Ferrite in Al-killed Low Carbon Steel

2016 
To verify the formation behaviors and mechanisms of intra-granular acicular ferrite( IAF) grains nucleated by Mg-Al-O in low carbon steel,the steels containing different Mg contents were refined in a vacuum induction furnace. The effect of Mg addition on the formation of IAF structure in Al-killed low carbon steel was investigated by optical microscope( OM) and scanning electron microscope with energy dispersive X-ray spectroscope( SEM-EDX). It reveals that the IAFs are only detected in Mg-added steels,and the volume fraction of IAF increases with the Mg concentration from 8 × 10-6 to 26 × 10-6. It shows that not only the MgO-Al2O3-MnS and MgO-Al2O3-P2O5 particles are the effective nucleation sites for IAF,but also the pure MgO·Al2O3 phase can promote the ferrite nucleation. A Mn-depletion zone( MDZ) is characterized adjacent to the MgO-Al2O3-MnS,which is believed to be one of the possible mechanisms to explain the IAF nucleation. The MDZ around the MgO-Al2O3-MnS inclusion would be induced by the Mn S precipitation on the inclusion. It seems that the ability of Mg-containing inclusions to induce the nucleation of ferrite might be attributed to a new mechanism,i. e.,the Prich zone formed on a few Mg-Al-O inclusions might be another factor for promoting the IAF formation.
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