An oxidized oligothiophene that forms π-stacks
1995
Abstract A dimethoxyterthiophene, substituted in the terminal α-positions with thioacetate groups, was synthesized and characterized. It was studied using cyclic voltammetry, ESR and optical spectroscopy in water solvent. A stable cation radical was formed using anodic or potassium ferrocyanide oxidation. In water the cation radical was aggregated into π-stacks, as signified by an optical conduction band in the NIR, shifts in the Vis π-π ∗ bands and an anisotropic ESR signal. This is the first example of such oligothiophene π-stacks. Evaporation of the water from an oxidized sample gave a black solid which had a four-point-probe conductivity as a pressed pellet of 10 −3 S cm −1 . Thus, oligothiophenes have been shown to provide molecular conductors and the possible importance of π-stacks in polythiophenes has been reinforced.
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