Ionic Organic Small Molecules as Hosts for Light-Emitting Electrochemical Cells
2018
Light-emitting electrochemical cells (LEECs) from ionic transition-metal complexes (iTMCs) offer the potential for high-efficiency electroluminescence in a simple, single-layer device. However, LEECs typically rely on the use of rare metal complexes. This has limited their cost effectiveness and put constraints on their applicability. With a view to leveraging the efficient emission of these complexes while mitigating costs, we describe here a host/guest LEEC strategy that relies on the use of carbazole (Cz)-based organic small-molecule hosts and iTMC guests. Three cationic host molecules were prepared via the coupling of 1-(4-bromophenyl)-2-phenylbenzimidazole (PBI-Br) with Cz. This has allowed a comparison between the hosts bearing methoxy (PBI-CzOMe) and tert-butyl (PBI-CztBu) substituents, as well as an unsubstituted analogue (PBI-CzH). Cyclic voltammetry and UV–visible absorption revealed that all three host materials have wide band gaps characterized by reversible oxidation and irreversible reductio...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
60
References
19
Citations
NaN
KQI