Catechins and their degradation products in grapes, husks, vinegar-wines, and corresponding vinegar III. Identification of phloroglucinol, phloroglucinol carboxylic acid und 2,4,6-trihydroxytoluene in vinegar-wines. Model-tests to determine the origination of these compounds in grapes or husks. Identification of the adulteration of vinegar-wines with after-wines