Palladium‐Catalyzed Diastereoselective Cyclization of the Allylic Precursors. A Concise Synthetic Route to 3‐Azabicyclo[3.3.0]octane and Hydroisoindole Skeletons.

Abstract A useful variant of palladium-catalyzed 1,2-diastereoselective cyclization of the allylic precursors based on the steric nature of the anion stabilizing groups has been developed. The 1,1,2-trisubstituted cycloalkane products have also been efficiently transformed into the azabicyclic systems.