9,9'-spiral acridine-containing compound and preparation method and application thereof
2017
The invention discloses the compound containing 9,9 ' spiral shell acridines, with 9,9 ' spiral shell acridines for core, 9,9 ' spiral shell acridines are combined with peripheral electrophilic Ar with Ar ' units.Contain 9 the invention also discloses above-mentioned, the preparation method of the compound of 9 ' spiral shell acridines, by the Ar units and Ar ' units that select different halogens to replace, with 10H, the spiral shell acridines of 10 ' H 9,9 ' carry out Buchwald Hartwig coupling reactions, copper catalysis halogenated aryl hydrocarbon ammoxidation, or the nucleophilic substitution under basic conditions obtains the compound containing 9,9 ' spiral shell acridines.The present invention discloses the application of the above-mentioned compound for containing 9,9 ' spiral shell acridines.The compound for containing 9,9 ' spiral shell acridines of the invention, with strong fluorescence, with certain electric conductivity, can be applied to make the luminescent layer of organic electroluminescent LED as illuminator.
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