Gold‐Catalyzed Aminoalkenylation of β‐Amino‐1,n‐Diynols to Cycloalkyl‐, Piperidinyl‐ and Pyranyl‐Fused Pyrroles

A synthetic method to prepare cycloalkyl-, piperidinyl- and pyranyl-fused pyrroles efficiently by gold(I)-catalyzed dehydrative aminoalkenylation of β-amino-1,n-diynols under mild conditions at room temperature is described.