Asymmetric total syntheses of (−)-tylophorine via the highly enantioselective intramolecular double michael reaction
1988
Abstract Asymmetric total synthesis of (−)-tylophorine ( 2 ) was achieved with a high enantioselectivity through the intramolecular double Michael reaction of the α, β-unsaturated ester ( 8 ) having a novel chiral auxiliary with tert.-butyldimethylsilyl trifluoromethanesulfonate and Et 3 N.
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