A Focusing Screen for Use in Photographing Ultraviolet Spectra

1905 
THE sensitive surface upon which Stokes projected the ultra-violet rays when observing metallic lines and absorption spectra consisted of a plate of plaster of Paris moistened with a paste of uranium phosphate acidified with phosphoric acid (Journ. Chem. Soc., vol. xvii., 1864). Soret used uranium glass and solutions of fluorescent substances such as aesculine in liquid cells. I have found that the most convenient and effective screen for examining spectra with a quartz spectrograph is one such as is used for the X-rays. It may be made as follows:—a photographic plate is first cleared of silver bromide by fixing and washing, and when the film is partly dry, but the gelatin still soft, it is dusted over with a powder of barium platinocyanide crystals, so as to be somewhat thickly coated with the salt. This is fixed in the dark slide of the camera. To focus a spectrum, the slide is tilted to the necessary angle, and a somewhat powerful focusing glass with a flat field is applied to the uncoated surface of the plate, when both the visible and ultra-violet spark spectra may be plainly seen by transmission, the latter by reason of the fluorescence excited. The focusing glass should be first carefully adjusted for any visible object on the other side of a plain glass plate, such as a fine hair fastened upon it, and the position of the eyepiece is then fixed. Suitable focusing glasses are those made by Dallmeyer and by Taylor, Taylor, and Hobson. When the spectrograph has been adjusted by means of the screen, the ultra-violet lines appear quite as sharp as those in the red and yellow, even the details in the group of cadmium lines between wave-lengths 2100 and 2400 are well defined, and a very fair photograph may be obtained; but for the most accurate focusing photography must be resorted to.
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