Mechanistic investigations of the phosphine-mediated nitrone deoxygenation reaction and its application in cyclic imine synthesis
2009
Carbohydrate-derived cyclic nitrones were deoxygenated to form the corresponding imines using tributylphosphine. Experimental and theoretical investigations by the way of MP2 calculations suggest a revision of the mechanism initially proposed by Kurtzweil and Beak for the triarylphosphine-mediated deoxygenation of nitrones.
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