Study of Magnetic Excitation in Singlet-Ground-State Magnets CsFeCl3 and RbFeCl3 by Nuclear Magnetic Relaxation

The temperature dependences of spin-lattice relaxation time T 1 of 133 Cs in CsFeCl 3 and 87 Rb in RbFeCl 3 were measured in the temperature range between 1.5 K and 22 K, at various fields up to 7 T applied parallel (or perpendicular) to the c -axis, and the analysis was made on the basis of the dynamical correlated-effective-field approximation. The mechanism of the nuclear magnetic relaxation is interpreted in terms of the magnetic fluctuations which are characterized by the singlet ground state system. In the field region where the phase transition occurs, T 1 -1 exhibited the tendency of divergence near T N , and this feature was ascribed to the transverse spin fluctuation associated with the mode softening at the K -point. It was found that the damping constant of the soft mode is remarkably affected by the occurrence of the magnetic ordering at lower temperature, and increases largely in the field region where the phase transition occurs.