Synthesis of β-Trifluoromethylated Ketones from Propargylic Alcohols by Visible Light Photoredox Catalysis.

Sehyun Park,Jung Min Joo,Eun Jin Cho

Synthesis of β-Trifluoromethylated Ketones from Propargylic Alcohols by Visible Light Photoredox Catalysis.

2015

Sehyun Park
Jung Min Joo
Eun Jin Cho

Trifluoromethylation of propargylic alcohols in the presence of a photocatalyst followed by double-bond migration/keto-enol tautomerization provides access to β-trifluoromethylketones.

Keywords:

Tautomer
Photocatalysis
Visible spectrum
Photoredox catalysis
Trifluoromethylation
Chemistry
Organic chemistry

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