Asymmetric Hydrogenation Reactions with Rh and Ru Complexes Bearing Phosphine—Phosphites with an Oxymethylene Backbone.

Patryk Artur Kleman,Mónica Vaquero,Inmaculada Arribas,Andrés Suárez,Eleuterio Álvarez,Antonio Pizzano

Asymmetric Hydrogenation Reactions with Rh and Ru Complexes Bearing Phosphine—Phosphites with an Oxymethylene Backbone.

2014

Patryk Artur Kleman
Mónica Vaquero
Inmaculada Arribas
Andrés Suárez
Eleuterio Álvarez
Antonio Pizzano

The title ligands show good activity in Rh-catalyzed hydrogenation reactions of olefinic substrates giving the corresponding products with enantioselectivities up to 96% enantiomeric excess.

Keywords:

Polymer chemistry
Asymmetric hydrogenation
Phosphine
Organic chemistry
Enantiomeric excess
Chemistry
Ligand

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