Photoselection in carbene formation by the use of polarized light

Ian R. Dunkin,D. Griller,Avtar S. Nazran,Daniel J. Northcott,John M. Park,A. H. Reddoch

Photoselection in carbene formation by the use of polarized light

1986

Ian R. Dunkin
D. Griller
Avtar S. Nazran
Daniel J. Northcott
John M. Park
A. H. Reddoch

Photolysis of diaryldiazomethanes in matrices using polarized light is highly selective, so that the e.s.r. spectra of the resulting carbenes show a remarkable degree of polarization.

Keywords:

Triplet state
Degree of polarization
Photodissociation
Polarization (waves)
Spectral line
Carbene
Photochemistry
Intersystem crossing
Chemistry
highly selective

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