Synthesis of Hydrazide Compounds Containing Ferrocene

2012 
Nine novel compounds 1,1′-bis[(2-benzoylhydrazinyl)carbonyl]-ferrocene(Ⅲ) were obtained from chlorocarbonyl ferrocene and aromatic formyl hydrazine by using microwave method.The structures of the title compounds have been determined by IR,1HNMR and ESI/MS techniques.The studies on the UV-Vis absorption spectroscopy show that the anion receptor Ⅲf has selective recognition for F-,CH3COO-,and Ⅲh,Ⅲi for F-,CH3COO-,H2PO4-.Preliminary biological activity test shows that ortho-substituted compounds Ⅲa,Ⅲb and Ⅲc have bacteriostatic action to Staphylococcus aureus and Escherichia coli.
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