Expanding the Porphycene Core: Modification and Metalation

Porphycenes, the first structural isomer of porphyrin, display unique chemical and photophysical properties. In this Account , we detail our group’s individual and collaborative efforts in elucidating further the chemical properties of porphycene. Particular emphasis will be placed on recent efforts devoted to expanding the porphycene core. 1 Introduction 2 Exploring the Chemistry of Porphycene 3 Synthesis and Metalation of an Expanded Porphycene 4 Conclusion