Stability and equation of state of face-centered cubic and hexagonal close packed phases of argon under pressure.
2021
The compression of argon is measured between 10 K and 296 K up to 20 GPa and and up to 114 GPa at 296 K in diamond anvil cells. Three samples conditioning are used: (1) single crystal sample directly compressed between the anvils, (2) powder sample directly compressed between the anvils, (3) single crystal sample compressed in a pressure medium. A partial transformation of the face-centered cubic (fcc) phase to a hexagonal close-packed (hcp) structure is observed above 4.2–13 GPa. Hcp phase forms through stacking faults in fcc-Ar and its amount depends on pressurizing conditions and starting fcc-Ar microstructure. The quasi-hydrostatic equation of state of the fcc phase is well described by a quasi-harmonic Mie–Gruneisen–Debye formalism, with the following 0 K parameters for Rydberg-Vinet equation: $$V_0$$
= 38.0 A
$$^3$$
/at, $$K_0$$
= 2.65 GPa, $$K'_0$$
= 7.423. Under the current experimental conditions, non-hydrostaticity affects measured P–V points mostly at moderate pressure (
$$\le$$
20 GPa).
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