Concentration and characteristics of depleted uranium in water, air and biological samples collected in Serbia and Montenegro

During the Balkan conflicts, in 1995 and 1999, depleted uranium (DU) rounds were employed and were left in the battlefield. Health concern is related to the risk arising from contamination of the environment with DU penetrators and dust. In order to evaluate the impact of DU on the environment and population in Serbia and Montenegro, radiological surveys of DU in water, air and biological samples were carried out over the period 27 October–5 November 2001. The uranium isotopic concentrations in biological samples collected in Serbia and Montenegro, mainly lichens and barks, were found to be in the range of 0.67–704 Bq kg � 1 for 238 U, 0.48–93.9 Bq kg � 1 for 234 U and 0.02–12.2 Bq kg � 1 for 235 U, showing uranium levels to be higher than in the samples collected at the control sites. Moreover, 236 U was detectable in some of the samples. The isotopic ratios of 234 U/ 238 U showed DU to be detectable in many biological samples at all examined sites, especially in Montenegro, indicating widespread ground-surface DU contamination, albeit at very lowlevel. The uranium isotopic concentrations in air obtained from the air filter samples collected in Serbia and Montenegro were found to be in the range of 1.99–42.1mBq m � 3 for 238 U, 0.96–38.0mBq m � 3 for 234 U, and 0.05–1.83mBq m � 3 for 235 U, being in the typical range of natural uranium values. Thus said, most of the air samples are DU positive, this fact agreeing well with the widespread DU contamination detected in the biological samples. The uranium concentrations in water samples collected in Serbia and Montenegro were found to be in the range of 0.40–21.9 mBq l � 1 for 238 U, 0.27–28.1 mBq l � 1 for 234 U, and 0.01–0.88 mBq l � 1 for 235 U, these values being much lower than those in mineral water found in central Italy and below the WHO guideline for drinking water. From a radiotoxicological point of view, at this moment there is no significant radiological risk related to these investigated sites in terms of possible DU contamination of water, air and/or plants. r 2005 Elsevier Ltd. All rights reserved.