P-Chirogenic silylphosphine-boranes: synthesis and phospha-Michael reactions
2015
Chiral and achiral silylphosphine-boranes were prep ared in high yields by reaction of phosphide boranes with halogenosilanes. Their reaction at roo m temperature with Michael acceptors afforded 1,4-addition products as silylenol ether o r ketone derivatives in good to excellent yields. In the case of the 2,3-dihalogeno-maleimides, the d ouble addition of silylphosphine-borane led to the corresponding trans-diphosphine-boranes in 86% yield. Noteworthy, the r eaction of Pchirogenic silylphosphine-boranes with enones affor ded the phospha-Michael adducts without racemization at the P-center. While the silylphosph ine-boranes have been scarcely described so far, these compounds demonstrate their great intere st for the synthesis of chiral and achiral functionalized organophosphorus compounds.
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