Rh(I)‐Catalyzed Reaction of Trifluoromethylketone N‐Tosylhydrazones and Arylboronates
2016
Rh(I)-Catalyzed synthesis of 1,1-difluoro-2,2-diarylalkenes from trifluoromethylketone N-tosylhydrazones and arylboronates is presented in this communication. This new synthetic method is based on the Rh(I)-carbene migratory insertion followed by β-fluoride elimination. In one particular case the protonation occurs instead of β-fluoride elimination, affording 2,2-diaryl trifluoroethane product.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
51
References
22
Citations
NaN
KQI