Rhodium-Catalyzed Enantioselective [2 + 2 + 1] Cycloaddition of 1,6-Enynes with Cyclopropylideneacetamides
2018
It has been established that a cationic rhodium(I)/(R)-tol-BINAP or (R)-BINAP complex catalyzes the enantioselective [2 + 2 + 1] cycloaddition of 1,6-enynes, possessing monosubstituted alkene units, with cyclopropylideneacetamides at room temperature through the elimination of ethylene to give bicyclic (cyclopent-2-en-1-ylidene)acetamides with high enantioselectivity.
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