Intramolecular benzoallene–alkyne cycloaddition initiated by site-selective SN2′ reaction of epoxytetracene en route to π-extended pyracylene
2019
A hydrogen halide promoted cascade reaction of epoxytetracene to afford halo-benzoindenotetracene including a benzoallene intermediate was developed. The remaining two alkynyl groups in benzoindenotetracene were further reacted with norbornadiene or arylamine through transition metal-catalyzed cyclization to give π-extended pyracylene derivatives.
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