UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(I) pincer complex

Simone A. Hauser,Jack Emerson-King,Scott Habershon,Adrian B. Chaplin

UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(I) pincer complex

2017

Simone A. Hauser
Jack Emerson-King
Scott Habershon
Adrian B. Chaplin

Iridium(I) carbonyl complex [Ir(2,6-(PtBu2CH2)2C6H3)(CO)] undergoes reversible C–H bond activation of benzene and a series of fluorobenzenes on UV irradiation. Exclusive ortho-selectivity is observed in reactions of fluorobenzene and 1,2-difluorobenzene.

Keywords:

Iridium
Organic chemistry
Benzene
Inorganic chemistry
Irradiation
Chemistry
Fluorobenzene
Photochemistry
Pincer movement
Hydrogen bond
Fluorobenzenes
c h bond

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