TMS Triflate Catalyzed Cleavage of Prenyl (3-Methylbut-2-enyl) Ester.

Mugio Nishizawa,Hirofumi Yamamoto,Ken Seo,Hiroshi Imagawa,Takumichi Sugihara

TMS Triflate Catalyzed Cleavage of Prenyl (3-Methylbut-2-enyl) Ester.

2010

Mugio Nishizawa
Hirofumi Yamamoto
Ken Seo
Hiroshi Imagawa
Takumichi Sugihara

Prenyl (3-methylbut-2-enyl) ester is catalytically cleaved by TMS triflate affording carboxylic acid and isoprene in high yield under mild conditions with high chemoselectivity without causing epimerization of the neighboring chiral center.

Keywords:

Trifluoromethanesulfonate
Cleavage (embryo)
Prenylation
Chemistry
Catalysis
Organic chemistry

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