Photoinduced Electron Transfer Dynamics in Triarylamine–Naphthalene Diimide Cascades

A series of dyads and triads of the A-D and A-D1-D2 type, respectively, containing triarylamine (TAA) donors and naphthalene diimide (NDI) acceptors, which are linked via triazole (Tz) heterocycles, were synthesized by Cu(I)-catalyzed azide alkyne cycloaddition (CuAAC). Upon photoexcitation, these systems undergo charge separation leading to long-lived charge-separated (CS) states. The population of these CS states was monitored using femtosecond and nanosecond transient absorption spectroscopy. The transient signals of the CS states of all triads and dyads feature biexponential decays in the nanosecond time regime with a short and a long component. These biexponential decays are the result of an ISC from the primarily populated 1CS state into the 3CS, from which charge recombination to the S0 state is forbidden by spin conservation rules. The existence of 3CS states in the triads was confirmed by strong magnetic field dependent transient absorption kinetics, while for the dyads no effect could be observe...