Precision of Electric-Field Gradient Predictions by Density Functional Theory and Implications for the Nuclear Quadrupole Moment and Its Error Bar of the 111Cd 245 keV 5/2+ Level

We present ab initio calculated electric-field gradient tensors at Cd sites in a set of simple yet diverse noncubic metals. By combining these predictions with carefully selected published experimental data, the nuclear quadrupole moment of the 245 keV 5/2+ level of 111Cd is determined to be 0.76(2) b. Knowing this quadrupole moment is important for time-differential perturbed angular correlation spectroscopy: decades of experimentally obtained nuclear quadrupole coupling constants for solids can now be more reliably converted into electronic structure information. For nuclear physics systematics, this is a rare opportunity to have reliable quadrupole moment information for a short-lived level that is not accessible to regular experimental methods. Much effort is spent on the determination of a meaningful error bar, which is an aspect that gained only recently more attention in the context of density functional theory predictions. This required assessing the numerical uncertainty in density functional the...