One‐Step Construction of N,P‐Codoped Porous Carbon Sheets/CoP Hybrids with Enhanced Lithium and Potassium Storage
2018
: Despite the desirable advancement in synthesizing transition-metal phosphides (TMPs)-based hybrid structures, most methods depend on foreign-template-based multistep procedures for tailoring the specific structure. Herein, a self-template and recrystallization-self-assembly strategy for the one-step synthesis of core-shell-like cobalt phosphide (CoP) nanoparticles embedded into nitrogen and phosphorus codoped porous carbon sheets (CoP⊂NPPCS), is first proposed. Relying on the unusual coordination ability of melamine with metal ions and the cooperative hydrogen bonding of melamine and phytic acid to form a 2D network, a self-synthesized single precursor can be attained. Importantly, this approach can be easily expanded to synthesize other TMPs⊂NPPCS. Due to the unique compositional and structural characteristics, these CoP⊂NPPCSs manifest outstanding electrochemical performances as anode materials for both lithium- and potassium-ion batteries. The unusual hybrid architecture, the high specific surface area, and porous features make the CoP⊂NPPCS attractive for other potential applications, such as supercapacitors and electrocatalysis.
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