Orthogonal light path-based equipment for online monitoring concentration of organic carbon/elemental carbon in PM (Particulate Matter) 2.5

The invention discloses orthogonal light path-based equipment for online monitoring the concentration of organic carbon/elemental carbon in PM (Particulate Matter) 2.5. The orthogonal light path-based equipment comprises an on-line sampling unit, a sample processing and detecting unit and an orthogonal light path system, and is characterized in that the sampling unit comprises a vacuum pump, a mass flow controller, a quartz filtering membrane, a ball valve, a volatilizable organic matter denuder, and a PM2.5 cutting head; the sample processing and detecting unit comprises a digestion furnace, an oxidation furnace, a gas path control network, a carrier gas source and a non-deviation infrared detector; the orthogonal light path system comprises a laser, a light beam splitter, a reference light path photoelectric detection unit, a quartz filtering membrane transmission light path photoelectric detection unit and a reflection light path photoelectric detection unit; and three gases of high-purity He, 5 percent O2/He and 5 percent CH4/He are required to be controlled by a gas path valve network by a singlechip. The orthogonal light path-based equipment is capable of simultaneously detecting light intensity values of incident laser, sampled reflected light and transmitted light of the quartz filtering membrane, and relatively accurately achieving the segmentation of the organic carbon and the elemental carbon.