Synthesis and Characterization of Two Extended High-dimensional Architectures Formed by Transition Metal–Glycine Complexes

2008 
Under the same experimental condition, changing the kinds of the transition metal (TM) of the reaction, we gained two new compounds: Na3[Cu(Gly)2][Cr(OH)6Mo6O18]·13H2O 1, and NaCo2(gly)6ClO4 2. Compound 1 exhibits an unusual three-dimensional (3D) network constructed from [Cr(OH)6Mo6O18]3− building blocks, trinuclear Na+ ions and [Cu(gly)2] coordination complexes as linkers, representing the first example of a 3D extended framework based on Anderson type polyanions and amino acid molecules. Compound 2 consists of an unusual 3D network grafted with Na[Co(gly)3]6 complexes. Moreover, compound 2 contains left-handed and right-handed helical chains.
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