Determination of chloromethane and dichloromethane in a tropical terrestrial mangrove forest in Brazil by measurements and modelling

Abstract Chloromethane (CH 3 Cl) and dichloromethane (CH 2 Cl 2 ) are known to have both natural and anthropogenic sources to the atmosphere. From recent studies it is known that tropical and sub tropical plants are primary sources of CH 3 Cl in the atmosphere. In order to quantify the biogenic emissions of CH 3 Cl and CH 2 Cl 2 from mangroves, field measurement were conducted in a tropical mangrove forest on the coast of Brazil. To the best of our knowledge these field measurements were the first of its kind conducted in the tropical mangrove ecosystem of Braganca. A mesoscale atmospheric model, MEsoscale TRAnsport and fluid (Stream) model (METRAS), was used to simulate passive tracers concentrations and to study the dependency of concentrations on type of emission function and meteorology. Model simulated concentrations were normalized using the observed field data. With the help of the mesoscale model results and the observed data the mangrove emissions were estimated at the local scale. By using this bottom-up approach the global emissions of CH 3 Cl and CH 2 Cl 2 from mangroves were quantified. The emission range obtained with different emission functions and different meteorology are 4–7 Gg yr −1 for CH 3 Cl and 1–2 Gg yr 2 for CH 2 Cl 2 . Based on the present study the mangroves contribute 0.3 percent of CH 2 Cl 2 and 0.2 percent of CH 3 Cl in the global emission budget. This study corroborates the study by Manley et al. (2007) which estimated that mangroves produce 0.3 percent of CH 3 Cl in the global emission budget. Although they contribute a small percentage in the global budget, their long lifetime enables them to contribute to the destruction of ozone in the stratosphere. From the detailed analyses of the model results it can be concluded that meteorology has a larger influence on the variability of concentrations than the temporal variability of the emission function.