Preparation of benzodiimidazole-containing covalent triazine frameworks for enhanced selective CO2 capture and separation

Abstract Covalent triazine frameworks (CTFs) were frequently prepared by carbonitriles polymerization reaction under the ionothermal condition, and the functionalized CTFs were achieved through the rational design of monomer to improve the gas capture and separation performance. In this paper, a class of porous benzodiimidazole-containing covalent triazine frameworks ( CTF-DIs ) was successfully prepared via ionothermal trimerizations from benzo[1,2- d :4,5- d ']diimidazole based dicyano monomer ( BCBDI ). The N 2 adsorption isotherms at 77 K reveal high BET surface areas of CTF-DIs up to 1877 m 2  g −1 . The effects of reaction temperature and the ratio of monomer to ZnCl 2 on the pore characteristics of the CTF-DIs were investigated. The highest uptake value for CO 2 is 89.2 cm 3  g −1 for CTF-DI-7 at 273 K and 1 bar. Excitingly, CTF-DI-6 demonstrates the highest CO 2 /N 2 selectivity of 53 and the significant CO 2 /CH 4 selectivity of 15 at 273 K and 1 bar, according to IAST, due to the existence of abundant active nitrogen species. These results clearly demonstrate the CTF-DIs are likely to be promising candidates for CO 2 capture and separation field.