Gold nanoparticle distribution in polyelectrolyte brushes loaded at different pH conditions

Composites made of polymer brushes with inclusions of gold nanoparticles (AuNPs) combine the responsive nature of polymer brushes with the optical properties of the AuNPs, which offers the possibility to be used as colorimetric sensors. To this end, it is crucial to know how AuNPs are distributed inside the brush. Here, this distribution was elucidated by neutron reflectometry with contrast variation and a self-consistent reflectivity analysis based on the analytical parameterization of the volume fraction profiles of all chemical components. In contrast to former studies, this analysis allows the determination of the spatial distribution of components separately from each other: polyelectrolyte, AuNP, and water. Cationic poly-[2-(Methacryloyloxy) ethyl] trimethylammonium chloride (PMETAC) brushes were loaded with 5 nm AuNPs, which were coated with a pH-sensitive capping. The pH was varied during the incubation of the brush in the AuNP suspension. At a lower pH, AuNPs form aggregates in suspension and are...