Efficient Protiodesilylation of Unactivated C(sp3)SiMe2Ph Bonds Using Tetrabutylammonium Fluoride.

Cheryl L. Heitzman,William T. Lambert,Eric Mertz,J. Brad Shotwell,Jennifer M. Tinsley,Porino Va,William R. Roush

Efficient Protiodesilylation of Unactivated C(sp3)SiMe2Ph Bonds Using Tetrabutylammonium Fluoride.

2005

Cheryl L. Heitzman
William T. Lambert
Eric Mertz
J. Brad Shotwell
Jennifer M. Tinsley
Porino Va
William R. Roush

The protiodesilylation of unactivated C(sp3)−SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates.

Keywords:

Tetrabutylammonium fluoride
Protonation
Polymer chemistry
Organic chemistry
Chemistry

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