Electrochemical properties of amorphous comb-shaped composite PEO polymer electrolyte
2002
Abstract The electrochemical behaviour of a polyethylene oxide (PEO)-based composite polymer electrolyte are studied. The crystallinity of the PEO is suppressed by using a comb-shaped polymer to improve polymer chain mobility. An amorphous comb-shaped polymer, ‘TEC-24’, with a side-chain content of 24 mol%, is designed and fine silica powder is dispersed within it to enhance the mechanical properties above the melting point. The composite polymer electrolyte has an ionic conductivity of 1.6×10 −4 and 1.6×10 −3 S cm −1 at 30 and 90 °C, respectively, with an electrochemical stability window close to 5.0 V, even at 80 °C (versus Li/Li + ). The polymer electrolyte is evaluated using CuS as a cathode material and shows better cycle performance than that obtained with a liquid electrolyte.
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