Metal-Free Autoxidative Nitrooxylation of Alkenyl Oximes with Molecular Oxygen
2016
A metal-free aerobic autoxidative nitrooxylation of alkenyl oximes mediated by tert-butyl nitrite is described. Molecular oxygen is used as the oxidizing reagent, avoiding use of organic trapping reagents such as 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO). The desired products were obtained in generally high yields.
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