Asymmetric Ring Opening of Epoxides with Cyanides Catalyzed by Chiral Binuclear Titanium Complexes.

Victor I. Maleev,Denis Chusov,Lidiya V. Yashkina,Nikolai S. Ikonnikov,Michail M. Il’in

Asymmetric Ring Opening of Epoxides with Cyanides Catalyzed by Chiral Binuclear Titanium Complexes.

2014

Victor I. Maleev
Denis Chusov
Lidiya V. Yashkina
Nikolai S. Ikonnikov
Michail M. Il’in

Titanium(IV) catalysts generated in situ from Ti(OiPr)4 and BINOL-based bis salen-compounds are developed and successfully used as recyclable catalysts for the asymmetric ring-opening reaction of epoxides with TmsCN.

Keywords:

Titanium
Chirality (chemistry)
Organic chemistry
Catalysis
Chemistry

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