A Porous Polycrystalline NiCo2Px As Highly Efficient Host For Sulfur Cathode of Li-S batteries
2021
Metal phosphides have exhibited great potential in the construction of highly efficient sulfur cathodes, benefiting from their high conductivity and catalytic property, which have been utilized to improve sulfur utilization, inhibit the drain of sulfur species during long-term cycling and facilitate the kinetics of the electrochemical reactions at the sulfur cathode of Li–S batteries. Here, porous polycrystalline NiCo2Px with an olivary morphology and robust structure has been fabricated via a facile derivation method. The NiCo2Px-derived sulfur cathode exhibited superior performance compared with the NiCo2O4 counterpart; besides high rate performance with a capacity of 610 mA h g−1 at 1C under an areal sulfur loading of 4.35 mg cm−2, areal capacity up to 8.54 mA h cm−2 was also achieved with high mass loadings of sulfur (5.79 mg cm−2) and a lean electrolyte (6 μL mg−1). The high conductivity and featured porous structure of NiCo2Px is considered to facilitate the electrochemical and kinetic behavior of the sulfur cathode, and its high catalytic activity was also preliminary established based on analyses of CV, EIS and symmetric batteries measurement. This work provides a new strategy for the fabrication of phosphides of elements in the iron family, broadens the application of metal phosphides in Li–S batteries, and deepens the understanding of the correlation between the morphology/phase structure of metal phosphides and the electrochemical performance of sulfur cathodes.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
55
References
0
Citations
NaN
KQI